This diagram goes by several other names including the metastable iron-carbon, Fe-C, iron-iron carbide, and the Fe-Fe3C phase diagrams. All the names point to the iron-carbon relationship and how it handles different temperatures. It came to be with the help of several scientists&#; work and the basis comes from a T-x diagram, which isn&#;t as comprehensive but was certainly the start of the full chart.

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Having this visual helps metallurgists, engineers, and manufacturers understand changes in an iron alloy&#;s microstructure, temperature phases and composition shifts - this isimportant to know when it comes to choosing the right alloys. This accurate and researched-backed diagram will guide you on when to harden, cool and heat different alloys, but it draws the line at offering any information on surrounding iron-carbon phases, i.e., you won&#;t find the non-equilibrium martensite phase here. And, it also won&#;t tell you anything about heating and cooling rates for different steels and phases, or exact phase properties.

How It Works

If you look at the chart, you&#;ll see the temperature and the carbon content (as a percentage of weight) are plotted on the Y and X axes respectively. There are also segments that horizontally span the graph, which represent a different phase in the changing of the iron-carbon microstructure. There are also temperatures like 723&#;, which is considered the critical or A1 temperature, meaning that any austenite in iron will turn into the eutectoid pearlite and double how much ferrite is in its structure. The chart also shows how two iron-carbon alloys can have the same chemical composition, they won&#;t necessarily have the same microstructure.They&#;ll be in varying phases at different temperatures.

Heat treatment is used to change the iron-carbon alloy&#;s microstructure, which is another reason you&#;ll need this diagram. If, say, you&#;re cooling pearlite at a rate of 200 &#; per minute, the hardness you&#;ll be able to achieve is 300 DPH. If you up the temperature to 400 &#; per minute for cooling, then you can increase the hardness to 400 DPH. This happens because carbon doesn&#;t get as much time to move through the lattice structure of pearlite. If you take it a step further and liquid quench the pearlite at 1,000 &#;, carbon can&#;t move at all and you can achieve the hardest and most brittle martensite structure.

Structures

Each phase&#;s atoms are arranged in a different way, and this arrangement is called the crystal structure. The properties, like strength or flexibility, will all depend on which structure category the phase falls into. Here&#;s a brief explanation of the five most common crystal structure types:

Body-centered cubic (BCC) crystal: This structure is like a cube with an atom in each corner and one slap bang in the middle. It&#;s strong but not very flexible, so materials with this type (like ferrite) tend to break easily, even though they&#;re most times hard. 

Body-centered tetragonal (BCT): This is very similar to BCC, the only difference being that it&#;s stretched in only one direction&#;something that makes it very strong and hard. Not that you&#;ll be surprised, but martensite has a BCT structure.

Face-centered cubic (FCC) crystal: Just like with BCC, with FCC there is an atom at each corner of the cube, but this one has an extra one in the middle of each of the cube&#;s faces. Materials that fall into this category (like austenite) are flexible and ductile.

Lamellar: Materials that have this structure have thin alternating layers made from two materials: soft and ductile ferrite, and hard but brittle cementite.

Orthorhombic: This is a rigid and hard structure that we can describe kind of like a stretched cube with sides of all different lengths. Cementite is orthorhombic, which is why it&#;s both tough and brittle.

Phases

The phases you&#;ll find expressed on the iron-carbon diagram are explained in the table below:

Cast Irons

Miguel Angel Yescas-Gonzalez and H. K. D. H. Bhadeshia

Cast irons typically contain 2-4 wt% of carbon with a high silicon concentrations and a greater concentration of impurities than steels. The carbon equivalent (CE) of a cast iron helps to distinguish the grey irons which cool into a microstructure containing graphite and and the white irons where the carbon is present mainly as cementite. The carbon equivalent is defined as:

A high cooling rate and a low carbon equivalent favours the formation of white cast iron whereas a low cooling rate or a high carbon equivalent promotes grey cast iron.

During solidification, the major proportion of the carbon precipitates in the form of graphite or cementite. When solidification is just complete, the precipitated phase is embedded in a matrix of austenite which has an equilibrium carbon concentration of about 2 wt%. On further cooling, the carbon concentration of the austenite decreases as more cementite or graphite precipitates from solid solution. For conventional cast irons, the austenite then decomposes into pearlite at the eutectoid temperature. However, in grey cast irons, if the cooling rate through the eutectoid temperature is sufficiently slow, then a completely ferritic matrix is obtained with the excess carbon being deposited on the already existing graphite.

White cast irons are hard and brittle; they cannot easily be machined.

The iron-carbon phase diagram showing the eutectic and eutectoid reactions. Reproduced with the permission of Jud Ready of the Georgia Tech. Joint Student Chapter of ASM/TMS.

Grey cast irons are softer with a microstructure of graphite in transformed-austenite and cementite matrix. The graphite flakes, which are rosettes in three dimensions, have a low density and hence compensate for the freezing contraction, thus giving good castings free from porosity.

The flakes of graphite have good damping characteristics and good machinability (because the graphite acts as a chip-breaker and lubricates the cutting tools. In applications involving wear, the graphite is beneficial because it helps retain lubricants. However, the flakes of graphite also are stress concentrators, leading to poor toughness. The recommended applied tensile stress is therefore only a quarter of its actual ultimate tensile strength.

Sulphur in cast irons is known to favour the formation of graphite flakes. The graphite can be induced to precipitate in a spheroidal shape by removing the sulphur from the melt using a small quantity of calcium carbide. This is followed by a minute addition of magnesium or cerium, which poisons the preferred growth directions and hence leads to isotropic growth resulting in spheroids of graphite. The calcuim treatment is necessary before the addition of magnesium since the latter also has an affinity for both sulphur and oxygen, whereas its spheroidising ability depends on its presence in solution in the liquid iron. The magnesium is frequently added as an alloy with iron and silicon (Fe-Si-Mg) rather than as pure magnesium.

However, magnesium tends to encourage the precipitation of cementite, so silicon is also added (in the form of ferro-silicon) to ensure the precipitation of carbon as graphite. The ferro-silicon is known as an inoculant.

Spheroidal graphite cast iron has excellent toughness and is used widely, for example in crankshafts.

The latest breakthrough in cast irons is where the matrix of spheroidal graphite cast iron is not pearlite, but bainite. This results in a major improvement in toughness and strength. The bainite is obtained by isothermal transformation of the austenite at temperatures below that at which pearlite forms.

You can click on the images to enlarge them. Very high resolution images (6 Mbytes each) can also be downloaded, as can the crystal structures of ferrite, cementite, graphite and austenite.

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Grey Cast Iron (Flake Graphite)

Grey cast iron, Fe-3.2C-2.5Si wt%, containing graphite flakes in a matrix which is pearlitic. The speckled white regions represent a phosphide eutectic. Etchant: Nital 2% Grey cast iron, Fe-3.2C-2.5Si wt%, containing graphite flakes in a matrix which is pearlitic. The lamellar structure of the pearlite can be resolved, appearing to consist of alternating layers of cementite and ferrite. The speckled white regions represent a phosphide eutectic. Etchant: Nital 2%  

Spheroidal Graphite Cast Iron

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The chemical composition of the cast iron is similar to that of the grey cast iron but with 0.05 wt% of magnesium. All samples are etched using 2% nital.

An illustration of the ductility of spheroidal graphite cast iron. Photograph reproduced from Physical Metallurgy of Engineering Materials , by E. R. Petty, with permission from the Institute of Materials. Spheroidal graphite cast iron, Fe-3.2C-2.5Si-0.05Mg wt%, containing graphite nodules in a matrix which is pearlitic. One of the nodules is surrounded by ferrite, simply because the region around the nodule is decarburised as carbon deposits on to the graphite. Etchant: Nital 2%  

Heat Treated Spheroidal Graphite Cast Iron

Spheroidal graphite cast iron usually has a pearlitic matrix. However, annealing causes the carbon in the pearlite to precipitate on to the existing graphite or to form further small graphite particles, leaving behind a ferritic matrix. This gives the iron even greater ductility. All samples are etched using 2% nital.

Graphite nodules in a ferritic matrix. Graphite nodules in a ferritic matrix. Some carbon deposited during tempering is also visible. Etchant: Nital 2%  

Austempered Ductile Cast Iron

The chemical composition of the cast iron is Fe-3.52C-2.51Si-0.49Mn-0.15Mo-0.31Cu wt%. All samples are etched using 2% nital. Colour micrographs are produced by first etching with 2% nital, followed by open air heat treatment of the metallographic sample at 270oC for 3 h. This oxidises the sample and produces interference colours which are phase dependent.

Ductile iron as-cast. Nodules of graphite, pearlite (dark islands) and ferrite (light background). Etchant: Nital 2% Ductile iron as-cast. Nodules of graphite, pearlite (dark islands) and ferrite (light background). Etchant: Nital 2%   Austenitised 950°C, austempered 350°C for 64 min. Austenitised at 950°C, austempered at 350°C for 64 min.  

The following images are of austempered ductile iron automobile components, provided by the Institute of Cast Metals Engineers. In order to avoid distortion, the crankshaft for the TVR sportscar is rough-machined after casting, heat-treated to produce the bainitic microstructure, and then properly machined. It is reported to have excellent fatigue properties; its damping characteristics due to graphite reduce engine noise.

The Ford Mustang suspension arm was made from austempered ductile iron in order to reduce weight, noise and cost. It was designed using finite element modelling to optimise strength and stiffness. Auminium alloys were considered but rejected because the component would then occupy a much larger space because of their lower strength.

The truck trailer suspension arm was originally made from welded steel, for use on transportation across the rugged Australian Outback. These failed at the welds and were associated with distortions which led to accelerated deterioration of the tyres. The suspension made from the cast austempered ductile iron has proved to be much more robust.

TVR Tuscan Speed 6, high-performance sports car with an austempered ductile iron crankshaft.
The austempered ductile iron crankshaft for the TVR sportscar.
Austempered ductile iron suspension arm for a Ford Mustang Cobra
A truck trailer suspension arm made from austempered ductile iron, Steele and Lincoln Foundry.

Blackheart Cast Iron

Blackheart cast iron is produced by heating white cast iron at 900-950oC for many days before cooling slowly. This results in a microstructure containing irregular though equiaxed nodules of graphite in a ferritic matrix. The term "blackheart" comes from the fact that the fracture surface has a grey or black appearance due to the presence of graphite at the surface. The purpose of the heat treatment is to increase the ductility of the cast iron. However, this process is now outdated since spheroidal graphite can be produced directly on casting by inoculating with magnesium or cerium. All samples are etched using 2% nital.

Blackheart cast iron. Blackheart cast iron. Etchant: Nital 2%  

Wear-Resistant High-Chromium Cast Iron

This cast iron is used in circumstances where a very high wear resistance is desirable. For example, during the violent crushing of rocks and minerals. It contains a combination of very strong carbide-forming alloying elements. Its chemical composition is, therefore, Fe-2.6C-17Cr-2Mo-2Ni wt%.

All samples are etched using Villela's reagent, which is a mixture of picric acid, hydrochloric acid and ethanol. The material from which these micrographs were obtained was kindly provided by Dr Arnoldo Bedolla-Jacuinde of Mexico. Details of the iron have been published in the International Journal of Cast Metals Research, 13 () 343-361.

The white phase is a chromium-rich carbide known as M7C3. The matrix consists of dendrites of austenite, some of which may have transformed into martensite. There may also be relatively small quantities of other alloy carbides. The white phase is a chromium-rich carbide known as M7C3. The matrix consists of dendrites of austenite, some of which may have transformed into martensite. There may also be relatively small quantities of other alloy carbides.  

Welding of Cast Irons

The casting process is never perfect, especially when dealing with large components. Instead of scrapping defective castings, they can often be repaired by welding. Naturally, the very high carbon concentration of typical cast irons causes difficulties by introducting brittle martensite in the heat-affected zone of the weld. It is therefore necessary to preheat to a temperature of about 450°C followed by slow cooling after welding, in order to avoid cracking.

The materials used as fillers during welding usually contain large nickel concentrations so that the resulting austenitic weld metal is not sensitive to the pick-up of carbon from the cast iron. The deposits are soft and can be machined to provide the necessary shape and finish. Of course, nickel is expensive so when making large repairs, the weld gap is first covered ('buttered') with the nickel-rich filler and then the remaining gap is filled with less expensive mild-steel filler metals.

Ironbridge

The world's first bridge made of iron in . The entire structure is made of cast iron. Photographs courtesy of Yokota Tomoyuki and family.

Ironbridge, made of cast iron
Ironbridge, made of cast iron
Ironbridge, made of cast iron
Ironbridge, made of cast iron
Ironbridge, made of cast iron. This photograph shows a crack.
The gorge.
A nearby power station.
Remains of a blast furnace (Coalbrookdale) built in .

More photos of Ironbridge

Coalbrookdale half-penny token,

The pictures below show a half-penny token coined in , one side showing the a ship passing under the world's first iron bridge. Iron ore and coal were transported via a canal, but the iron-works at Ketley were 22 m above this canal. So an "inclined plane" (2nd image) was built so that boats could be lifted via a cradle and a lock into the upper part of the canal that led to the iron-works.

The token was made available courtesy of Michael Cook.

III

Cast iron has a "solid feel" and has an appealing appearance. There are many conventional applications of cast iron.

Cast Iron in a Computer Mouse

The following photographs have kindly been provided by Ben Dennis-Smither, Frank Clarke and Mohamed Sherif.

Disection of a computer mouse. The item of interest is the roller ball.
The microstructure of the roller ball, which is made of cast iron, The flakes of graphite are surrounded by ferrite, the brown is the peralite, and there is also the product of the lediburite eutectic which is not clear at this magnification.

The pearlite is resolved in some regions where the sectioning plane makes a glancing angle to the lamellae. The lediburite eutectic is highlighted by the arrows. At high temperatures this is a mixture of austenite and cementite formed from liquid. The austenite subsequently decomposes to pearlite.
The ball is made of cast iron presumably because it is relatively hard.

Cast Iron Jewellery

The following photographs were kindly provided by Jim Charles.

Ancient cast iron jewellery
Ancient cast iron jewellery

Patterns in Cast Iron Components and Surroundings

Photographs courtesy of Mathew Peet

Cast Iron in Buenos Aires, Argentina

Puerot Madero, Buenous Aires, Argentina
Puerot Madero, Buenous Aires, Argentina. Massive cast iron moorings decorate the shore, made in a foundry in Cardiff, Wales, U.K.
Puerot Madero, Buenous Aires, Argentina. Massive cast iron moorings decorate the shore, made in a foundry in Cardiff, Wales, U.K.
Puerot Madero, Buenous Aires, Argentina
The Bridge of Woman (Puente de La Mujer), Buenos Aires, Argentina

Cast Iron Gate of Guell Palace by Gaudi in Barcelona

The following photographs have kindly been provided by Francisca Caballero and Carlos Capdevila Montes.

Gate of Guell Palace by Gaudi in Barcelona
Cast iron gate of Guell Palace by Gaudi in Barcelona
Cast iron gate of Guell Palace by Gaudi in Barcelona
Cast iron gate of Guell Palace by Gaudi in Barcelona
Cast iron gate of Guell Palace by Gaudi in Barcelona
Cast iron gate of Guell Palace by Gaudi in Barcelona
Cast iron gate of Guell Palace by Gaudi in Barcelona
Cast iron gate of Guell Palace by Gaudi in Barcelona

Review of a book on Cast Irons containing Rare Earths.

Graphitisation

Metallography of cast irons.

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